9-TRIFLUOROACETYLANTHRACENE

  • Name: 9-TRIFLUOROACETYLANTHRACENE
  • CAS: 53531-31-0
  • Purity: 99%
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Details

Quality manufacturer supply 9-TRIFLUOROACETYLANTHRACENE 53531-31-0 in stock with high standard

  • Molecular Formula: C16H9 F3 O
  • Molecular Weight: 274.242
  • Vapor Pressure: 3.48E-06mmHg at 25°C 
  • Melting Point: 84-86 °C(lit.)
     
  • Boiling Point: 386.7°Cat760mmHg 
  • Flash Point: 189.7°C 
  • PSA： 17.07000 
  • Density: 1.333g/cm3 
  • LogP: 4.73800 

9-TRIFLUOROACETYLANTHRACENE(Cas 53531-31-0) Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 313, 1979 DOI: 10.1021/jo01316a041Tetrahedron Letters, 36, p. 9117, 1995 DOI: 10.1016/0040-4039(95)01978-Q

InChI:InChI=1/C16H9F3O/c17-16(18,19)15(20)14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9H

53531-31-0 Relevant articles

Oxidation of fluoroalkyl alcohols using sodium hypochlorite pentahydrate [1]

Kirihara, Masayuki,Suzuki, Katsuya,Nakakura, Kana,Saito, Katsuya,Nakamura, Riho,Tujimoto, Kazuki,Sakamoto, Yugo,Kikkawa, You,Shimazu, Hideo,Kimura, Yoshikazu

, (2021/02/05)

Fluoroalkyl alcohols are effectivity oxi...

Method for expedient synthesis of [18F]-labeled α-trifluoromethyl ketones

-

Page/Page column 7, (2008/06/13)

The present invention is directed to a c...

A new method for oxidation of various alcohols to the corresponding carbonyl compounds by using n-t-butylbenzenesulfinimidoyl chloride

Matsuo, Jun-Ichi,Iida, Daisuke,Tatani, Kazuya,Mukaiyama, Teruaki

, p. 223 - 234 (2007/10/03)

Various primary and secondary alcohols w...

Acylation of activated aromatic substrates under mild conditions with (RCO)2O/Me2S/BF3

Kiselyov, Alexander S.

, p. 4005 - 4008 (2007/10/02)

An efficient procedure for acylation and...

53531-31-0 Process route

1-(9-anthryl)-2,2,2-trifluoroethanol
60686-64-8,65487-67-4

1-(9-anthryl)-2,2,2-trifluoroethanol

1-(9-anthracenyl)-2,2,2-trifluoroethan-1-one
53531-31-0

1-(9-anthracenyl)-2,2,2-trifluoroethan-1-one

Conditions
Conditions Yield
With N-(tert-butyl)benzenesulfinimidoyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at -78 - 20 ℃; for 2h;
81%
With cyclic iodinane oxide; In dichloromethane; for 1h; Ambient temperature;
73%
With potassium hydrogensulfate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite pentahydrate; In acetonitrile; at 0 ℃; for 0.333333h;
74 %Spectr.
anthracene
120-12-7

anthracene

trifluoroacetyl triflate
68602-57-3

trifluoroacetyl triflate

1-(9-anthracenyl)-2,2,2-trifluoroethan-1-one
53531-31-0

1-(9-anthracenyl)-2,2,2-trifluoroethan-1-one

Conditions
Conditions Yield
With 2,6-di-tert-butyl-4-methylpyridine; In benzene; at 80 ℃; for 44h;
81 % Spectr.

53531-31-0 Upstream products

  • 120-12-7
    120-12-7

    anthracene

  • 68602-57-3
    68602-57-3

    trifluoroacetyl triflate

  • 383-63-1
    383-63-1

    ethyl trifluoroacetate,

  • 1564-64-3
    1564-64-3

    9-Bromoanthracene

53531-31-0 Downstream products

  • 60646-30-2
    60646-30-2

    (S)-2,2,2-trifluro-1-(anthryl)ethanol

  • 53531-34-3
    53531-34-3

    (R)-2,2,2-trifluoro-1-(9-anthryl)ethanol

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